Synthesis, Structure, and Synthetic Potential of Arenediazonium Trifluoromethanesulfonates as Stable and Safe Diazonium Salts,European Journal of Organic Chemistry

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Synthesis, Structure, and Synthetic Potential of Arenediazonium Trifluoromethanesulfonates as Stable and Safe Diazonium Salts
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-08-28 , DOI: 10.1002/ejoc.201800887
Victor D. Filimonov ₁ , Elena A. Krasnokutskaya ₁ , Assia Zh. Kassanova _{1,

2} , Valentina A. Fedorova ₁ , Ksenia S. Stankevich ₁ , Nikolay G. Naumov _{3,

4} , Alexander A. Bondarev ₅ , Veronika A. Kataeva ₁

Affiliation

A variety of stable, safe, and soluble arenediazonium triflates ArN₂⁺ TfO^– were obtained easily by diazotization of anilines with tert‐butyl nitrite in the presence of triflic acid. They are highly reactive, forming aromatic iodides, azides, and boronic acids, and also undergo an unusual metal‐free chloro‐dediazonization with chloroform and CCl₄.

中文翻译：

稳定，安全的重氮盐三氟甲烷磺酸亚芳基重氮鎓盐的合成，结构和合成潜力

在三氟甲磺酸存在下，通过亚硝酸叔丁酯对苯胺进行重氮化，可轻松获得各种稳定，安全且可溶的芳族_二氮杂三氟甲磺酸盐ArN ₂⁺ TfO ^–。它们具有很高的反应活性，形成芳族碘化物，叠氮化物和硼酸，并且还与氯仿和CCl ₄进行了不同寻常的无金属无氯二氮杂脱氮反应。

更新日期：2018-08-28

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