Tetra-n-butylammonium bromide (TBAB)-initiated carbonylation–peroxidation of styrene derivatives with aldehydes and hydroperoxides†,Organic Chemistry Frontiers

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Tetra-n-butylammonium bromide (TBAB)-initiated carbonylation–peroxidation of styrene derivatives with aldehydes and hydroperoxides†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2018-07-16 00:00:00 , DOI: 10.1039/c8qo00525g
Yao Yao _{1,

2,

3,

4,

5} , Zhen Wang _{1,

2,

3,

4,

5} , Bin Wang _{1,

2,

3,

4,

5}

Affiliation

Tetra-n-butylammonium bromide (TBAB)-catalyzed carbonylation–peroxidation of styrene derivatives is described, which allows for the synthesis of β-peroxy ketones under mild conditions. The ease of handling, low cost, and environmentally friendly bromine catalyst made this protocol very practical. Mechanistic studies revealed that it was a bromine initiated radical difunctionalization of alkenes.

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