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Copper‐Catalyzed Asymmetric Ring‐Opening of Cyclic Diaryliodonium with Benzylic and Aliphatic Amines
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-08-02 , DOI: 10.1002/adsc.201800637
Shibo Xu 1 , Kun Zhao 1 , Zhenhua Gu 1
Affiliation  

A Cu‐catalyzed asymmetric ring‐opening reaction between cyclic diaryliodonium and benzylic or aliphatic amines has been developed. At low concentration of the amines, realized by either mixing the amines with Lewis acid or slow addition of the amines, the reaction afforded the products in high enantioselectivity.

中文翻译:

铜催化苯并胺和脂肪胺的环状二芳环鎓的不对称开环

已开发出环状二芳基碘鎓与苄基或脂肪族胺之间的Cu催化不对称开环反应。在低浓度的胺下,通过将胺与路易斯酸混合或缓慢加入胺来实现,该反应提供了高对映选择性的产物。
更新日期:2018-08-02
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