Copper‐Catalyzed Asymmetric Ring‐Opening of Cyclic Diaryliodonium with Benzylic and Aliphatic Amines,Advanced Synthesis & Catalysis

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Copper‐Catalyzed Asymmetric Ring‐Opening of Cyclic Diaryliodonium with Benzylic and Aliphatic Amines
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-08-02 , DOI: 10.1002/adsc.201800637
Shibo Xu ₁ , Kun Zhao ₁ , Zhenhua Gu ₁

Affiliation

A Cu‐catalyzed asymmetric ring‐opening reaction between cyclic diaryliodonium and benzylic or aliphatic amines has been developed. At low concentration of the amines, realized by either mixing the amines with Lewis acid or slow addition of the amines, the reaction afforded the products in high enantioselectivity.

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