Molecular Borromean Rings Based on Half-Sandwich Organometallic Rectangles,Accounts of Chemical Research

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Molecular Borromean Rings Based on Half-Sandwich Organometallic Rectangles
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-07-10 00:00:00 , DOI: 10.1021/acs.accounts.8b00220
Ye Lu ₁ , Hai-Ning Zhang ₁ , Guo-Xin Jin ₁

Affiliation

Over the last two decades, interlocked molecular species have received considerable attention, not only because of their intriguing structures and topological importance, but also because of their potential applications as smart materials, nanoscale devices, and molecular machines. Through judicious choice of metal centers and their adjoining ligands, a range of interesting interlocked structures have been realized by coordination-driven self-assembly. In addition, researchers have extensively developed synthetic methodologies for the construction of organized self-assemblies. One fascinating and challenging synthetic target in this field is the family of molecular Borromean rings, which consist of three chemically independent rings that are locked in such a way that no two of the three rings are linked with each other.

中文翻译：

基于半三明治有机金属矩形的分子硼烷环。

在过去的二十年中，互锁的分子物种受到了极大的关注，这不仅是因为其有趣的结构和拓扑重要性，而且还因为它们作为智能材料，纳米级设备和分子机器的潜在应用。通过对金属中心及其相邻配体的明智选择，通过协调驱动的自组装，实现了一系列有趣的互锁结构。此外，研究人员已经广泛开发了用于构建有组织的自组装体的综合方法。该领域中一个引人入胜且具有挑战性的合成靶标是分子Borromean环家族，该环由三个化学上独立的环组成，这些环以这样的方式锁定：三个环中没有两个彼此连接。

更新日期：2018-07-10

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