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Study to Explore Inclusion Complexes of α- and β-Cyclodextrin Molecules with 3-Octyl-1-Methylimidazolium Bromide with the Manifestation of Hydrophobic and Hydrophilic Interactions
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-07-11 , DOI: 10.1016/j.cplett.2018.07.019
Kalipada Sarkar , Biraj Kumar Barman , Mahendra Nath Roy

Inclusion complex formation of 3-octyl-1-methylimidazolium bromide (OMImBr) into α- and β-cyclodextrins has been investigated with physicochemical methods and spectroscopic techniques. Spectroscopic studies like FT-IR, UV and Visible and 1H NMR, 2D ROESY NMR were carried out to confirm the formation of inclusion complexes. The surface tension and conductivity measurements reveal the 1:1 stoichiometry of the inclusion complex. The well-known Job’s method and Benesi–Hildebrand method from UV study was also applied for confirmation the host-guest stoichiometry.



中文翻译:

探索具有疏水和亲水相互作用的α-和β-环糊精分子与3-辛基-1-甲基咪唑鎓溴化物的包合物的研究

用物理化学方法和光谱技术研究了3-辛基-1-甲基咪唑鎓溴化物(OMImBr)在α-和β-环糊精中的包合物形成。进行了光谱研究,如FT-IR,UV和Visible以及1 H NMR,2D ROESY NMR,以确认包合物的形成。表面张力和电导率的测量结果表明夹杂物的化学计量比为1:1。紫外线研究中著名的Job's方法和Benesi–Hildebrand方法也被用于确认主客体化学计量。

更新日期:2018-07-12
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