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CO and C3H6 oxidation over platinum-group metal (PGM) catalysts supported on Mn-modified hexagonal YbFeO3
Catalysis Today ( IF 5.2 ) Pub Date : 2018-07-10 , DOI: 10.1016/j.cattod.2018.07.026
Saburo Hosokawa , Shogo Matsumoto , Kenya Onishi , Hiroyuki Asakura , Kentaro Teramura , Tsunehiro Tanaka

The oxidations of CO and C3H6 are important model reactions for environmental cleanup reactions such as the purification of automotive exhaust gases from diesel engine or of volatile organic compounds. Mn-modified hexagonal YbFeO3 (Mn-h-YbFeO3), synthesized by a solvothermal method, exhibits excellent catalytic activities for these oxidations despite the absence of platinum-group metal (PGM) loading. The activity of Mn-h-YbFeO3 itself is dramatically enhanced by the addition of a small amount of Pd or Ru; these species supported on the Mn-h-YbFeO3 act as promoters that improve the CO- or C3H6- adsorption/desorption ability and the oxygen release property from the Mn-h-YbFeO3. PGM/Mn-h-YbFeO3 catalysts show much higher catalytic activities than Al2O3-supported PGM catalysts in which Al2O3 support is inert for these reactions. We expect that the establishment of such promoter effects for catalyst support having high catalytic activity will provide novel guidelines for reducing the use of precious-metal resources.



中文翻译:

Mn修饰的六边形YbFeO 3负载的铂族金属(PGM)催化剂上的CO和C 3 H 6氧化

CO和C 3 H 6的氧化是环境净化反应的重要模型反应,例如净化柴油发动机的汽车废气或挥发性有机化合物。尽管没有铂族金属(PGM)的负载,但通过溶剂热法合成的Mn改性六角形YbFeO 3(Mn- h -YbFeO 3)表现出出色的催化活性。Mn- h - YbFeO 3本身的活性通过添加少量的Pd或Ru而显着提高。这些负载在Mn- h -YbFeO 3上的物质可作为促进CO-或C 3的促进剂H 6的吸附/解吸能力和Mn- h -YbFeO 3的氧释放性能。PGM / Mn- h - YbFeO 3催化剂显示出比Al 2 O 3负载的PGM催化剂高的催化活性,其中Al 2 O 3载体对于这些反应是惰性的。我们期望建立具有高催化活性的催化剂载体的这种促进作用将为减少贵金属资源的使用提供新的指导方针。

更新日期:2018-07-10
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