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Stereocontrolled Formal Synthesis of Platencin
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-08-21 , DOI: 10.1002/ejoc.201800806
Day-Shin Hsu,Tai-Yu Hwang

A stereocontrolled construction of the tricyclic core of platencin was accomplished from a bromophenol derivative in 11 steps by means of dearomatization/Diels–Alder reaction and an aldol condensation. All of the necessary stereogenic centers of the tricyclic core of platencin were established in one step by the Diels–Alder reaction.
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中文翻译:

立体控制形式的Platencin合成

通过脱芳香化反应/ Diels-Alder反应和醛醇缩合反应,由溴酚衍生物以11个步骤完成了Platencin三环核的立体控制结构。通过Diels–Alder反应一步一步建立了Platencin三环核心的所有必要的立体异构中心。
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更新日期:2018-08-21
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