Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage,Advanced Materials

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Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage
Advanced Materials ( IF 27.4 ) Pub Date : 2018-07-08 , DOI: 10.1002/adma.201705146
Arindam Indra ₁ , Taeseup Song ₁ , Ungyu Paik ₁

Affiliation

Exploring new materials with high efficiency and durability is the major requirement in the field of sustainable energy conversion and storage systems. Numerous techniques have been developed in last three decades to enhance the efficiency of the catalyst systems, control over the composition, structure, surface area, pore size, and moreover morphology of the particles. In this respect, metal organic framework (MOF) derived catalysts are emerged as the finest materials with tunable properties and activities for the energy conversion and storage. Recently, several nano‐ or microstructures of metal oxides, chalcogenides, phosphides, nitrides, carbides, alloys, carbon materials, or their hybrids are explored for the electrochemical energy conversion like oxygen evolution, hydrogen evolution, oxygen reduction, or battery materials. Interest on the efficient energy storage system is also growing looking at the practical applications. Though, several reviews are available on the synthesis and application of MOF and MOF derived materials, their applications for the electrochemical energy conversion and storage is totally a new field of research and developed recently. This review focuses on the systematic design of the materials from MOF and control over their inherent properties to enhance the electrochemical performances.

中文翻译：

金属有机框架衍生材料：能量转换和存储的进展与前景

在可持续的能源转换和存储系统领域中，开发具有高效率和耐久性的新材料是主要要求。在过去的三十年中，已经开发了许多技术来提高催化剂体系的效率，控制组成，结构，表面积，孔径，以及颗粒的形态。在这方面，金属有机骨架（MOF）衍生的催化剂作为具有可调节特性和用于能量转换和存储的活性的最佳材料而出现。最近，人们探索了几种金属或纳米结构的金属氧化物，硫属元素化物，磷化物，氮化物，碳化物，合金，碳材料或其混合物，以进行电化学能量转换，例如氧气释放，氢气释放，氧气还原或电池材料。在实际应用中，人们对高效储能系统的兴趣也越来越高。尽管有一些关于MOF和MOF衍生材料的合成和应用的评论，但它们在电化学能量转换和存储中的应用是一个全新的研究领域，并且最近得到了发展。这篇综述着重于MOF材料的系统设计以及对材料固有特性的控制，以增强电化学性能。

更新日期：2018-07-08

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