[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects†‡,Chemical Communications

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[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects†‡
Chemical Communications ( IF 4.3 ) Pub Date : 2018-07-07 00:00:00 , DOI: 10.1039/c8cc03009j
T. W. Schneider _{1,

2,

3,

4} , M. T. Hren _{1,

2,

3,

4} , M. Z. Ertem _{4,

5,

6,

7,

8} , A. M. Angeles-Boza _{1,

2,

3,

4,

9}

Affiliation

In this work, we examine the use of competitive ¹³C kinetic isotope effects (¹³C KIEs) on CO₂ reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined ¹³C KIE measurements and theoretical calculations methodology for probing CO₂ conversion reactions.

中文翻译：

[Ru ^II（tpy ）（bpy）Cl] ^+-催化还原二氧化碳。碳13动力学同位素效应的机理见解† ‡

在这项工作中，我们研究了在产生CO和甲酸的CO ₂还原反应中使用竞争性¹³ C动力学同位素效应（¹³ C KIEs）作为制定反应机理的手段。此处报道的发现标志着用于探测CO ₂转化反应的结合的¹³ C KIE测量和理论计算方法的进一步发展。

更新日期：2018-07-07

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