C–H Bond Activation by a Ruthenium(II) β‐Diketonate Complex: A Mechanistic Study,European Journal of Organic Chemistry

当前位置： X-MOL 学术 › Eur. J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

C–H Bond Activation by a Ruthenium(II) β‐Diketonate Complex: A Mechanistic Study
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-08-17 , DOI: 10.1002/ejoc.201800787
Anamarija Briš _{1,

2} , Iztok Turel ₃ , Jana Roithová _{1,

4}

Affiliation

2‐Phenylpyridine C–H activation catalysed by a ruthenium(II) β‐diketonate complex was studied by ESI‐MS and CID. We have identified [Ru(β‐diketonate)(^CTPhPy)Cl]⁺ as an active intermediate, and its collisional activation leads to C–H activation. DFT calculations were performed to identify all ruthenium intermediates along the C–H activation reaction pathway.

中文翻译：

β-二酮钌（II）络合物活化C–H键的机理研究

通过ESI-MS和CID研究了钌（II）β-二酮酸酯络合物催化的2-苯基吡啶CH–H活化。我们已经确定[Ru（β-二酮酸酯）（^CT PhPy）Cl] ⁺为活性中间体，其碰撞活化导致C–H活化。进行了DFT计算，以确定沿C–H活化反应途径的所有钌中间体。

更新日期：2018-08-17

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11