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Synthesis and Characterization of Yellow Pigments of Bi1.7RE0.3W0.7Mo0.3O6 (RE = Y, Yb, Gd, Lu) with High NIR Reflectance
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2018-07-06 00:00:00 , DOI: 10.1021/acssuschemeng.8b02049 Bin Huang 1 , Yu Xiao 1, 2 , Haiyue Zhou 1 , Jinqing Chen 2 , Xiaoqi Sun 1, 3
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2018-07-06 00:00:00 , DOI: 10.1021/acssuschemeng.8b02049 Bin Huang 1 , Yu Xiao 1, 2 , Haiyue Zhou 1 , Jinqing Chen 2 , Xiaoqi Sun 1, 3
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Brilliant yellow-orange pigments based on the formula Bi1.7RE0.3W0.7Mo0.3O6 (RE = Y, Yb, Gd, Lu) are developed by the traditional solid-state reaction method. Relevant techniques are used for characterization of the crystal structure, morphology feature, reflectance property, and color performance of the prepared pigment. The doping of RE/Mo in Bi2WO6 results in the colors of pigments varying from faint yellow to brilliant yellow-orange. Compared with Bi2WO6 pigment, the typical pigment of Bi1.7Lu0.3W0.7Mo0.3O6 greatly improves the yellow hue component (b*) value to be 72.03. Moreover, the NIR reflectances of all of the samples are higher than 95% , and their NIR solar reflectances are above 94%. The typical pigment of Bi1.7Lu0.3W0.7Mo0.3O6 coated on galvanized sheet exhibits excellent coloring performance with a high NIR solar reflectance (83.32%). The acid/alkali resistance studies reveal that the pigments are chemically stable under the atrocious weather conditions. Thus, the superior performances of synthesized pigments have exhibited potential for energy savings.
中文翻译：
具有高近红外反射率的Bi 1.7 RE 0.3 W 0.7 Mo 0.3 O 6（RE = Y，Yb，Gd，Lu）黄色颜料的合成与表征
通过传统的固态反应方法，开发了基于分子式Bi 1.7 RE 0.3 W 0.7 Mo 0.3 O 6（RE = Y，Yb，Gd，Lu）的亮橙色橙颜料。相关技术用于表征所制备颜料的晶体结构，形态特征，反射特性和色彩性能。在Bi 2 WO 6中掺杂RE / Mo会导致颜料的颜色从微弱的黄色到亮橙色的橘黄色。与Bi 2 WO 6颜料相比，Bi 1.7 Lu 0.3 W 0.7 Mo 0.3的典型颜料O 6大大改善了黄色色调分量（b *）的值为72.03。而且，所有样品的NIR反射率均高于95％，并且它们的NIR太阳反射率均高于94％。涂在镀锌板上的典型Bi 1.7 Lu 0.3 W 0.7 W 0.7 Mo 0.3 O 6颜料具有出色的着色性能和高NIR太阳反射率（83.32％）。耐酸/碱性能研究表明，该颜料在恶劣的天气条件下化学稳定。因此，合成颜料的优异性能已显示出节能的潜力。
更新日期：2018-07-06
中文翻译：
具有高近红外反射率的Bi 1.7 RE 0.3 W 0.7 Mo 0.3 O 6（RE = Y，Yb，Gd，Lu）黄色颜料的合成与表征
通过传统的固态反应方法，开发了基于分子式Bi 1.7 RE 0.3 W 0.7 Mo 0.3 O 6（RE = Y，Yb，Gd，Lu）的亮橙色橙颜料。相关技术用于表征所制备颜料的晶体结构，形态特征，反射特性和色彩性能。在Bi 2 WO 6中掺杂RE / Mo会导致颜料的颜色从微弱的黄色到亮橙色的橘黄色。与Bi 2 WO 6颜料相比，Bi 1.7 Lu 0.3 W 0.7 Mo 0.3的典型颜料O 6大大改善了黄色色调分量（b *）的值为72.03。而且，所有样品的NIR反射率均高于95％，并且它们的NIR太阳反射率均高于94％。涂在镀锌板上的典型Bi 1.7 Lu 0.3 W 0.7 W 0.7 Mo 0.3 O 6颜料具有出色的着色性能和高NIR太阳反射率（83.32％）。耐酸/碱性能研究表明，该颜料在恶劣的天气条件下化学稳定。因此，合成颜料的优异性能已显示出节能的潜力。
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