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N-doped CMK-3 anchored with SnS2 nanosheets as anode of lithium ion batteries with superior cyclic performance and enhanced reversible capacity
Journal of Solid State Chemistry ( IF 3.3 ) Pub Date : 2018-06-15 , DOI: 10.1016/j.jssc.2018.06.015
Jingchao Liang , Han Li , Zhipeng Sun , Dianzeng Jia

The composites of N-doped ordered mesoporous carbon (N-CMK-3) anchored with tin disulfide (SnS2) nanosheets (NSs) have been synthesized via a maneuverable hot bath method at low temperature. The as-synthesized SnS2@N-CMK-3 composites exhibit a hierarchical structure with two dimensional (2D) SnS2 nanosheets uniformly grown on N-CMK-3, leading to a large specific area (126.7 m2 g−1) with mesoscale porosity. As anode material for lithium ion batteries (LIBs), SnS2@N-CMK-3 composite exhibits a high initial capacity of 1438.9 mA h g−1 (200 mA g−1). Moreover, the electrochemical performance remained at 618.9 mA h g−1 after 200 cycles, which are significantly higher than that of the pristine SnS2. The outstanding electrochemical properties might be due to the 2D nanosheet-morphology feature of SnS2 and the addition of N-CMK-3 that could availably inhibit the agglomeration of active substances and raise the conductivity of the composite electrode.



中文翻译:

掺有SnS 2纳米片的N掺杂CMK-3作为锂离子电池的负极,具有出色的循环性能和增强的可逆容量

通过低温热浴法合成了掺有二硫化锡(SnS 2)纳米片(NSs)的N掺杂有序介孔碳(N-CMK-3)的复合材料。刚合成的SnS 2 @ N-CMK-3复合材料表现出具有在N-CMK-3上均匀生长的二维(2D)SnS 2纳米片的分层结构,从而导致较大的比表面积(126.7 m 2 g -1)。中尺度孔隙度。作为锂离子电池(LIB)的负极材料,SnS 2 @ N-CMK-3复合材料具有1438.9 mA h g -1(200 mA g -1)的高初始容量。此外,电化学性能保持在618.9 mA h g -1200次循环后,这明显高于原始的SnS 2。出色的电化学性能可能是由于SnS 2的2D纳米片形态特征和添加的N-CMK-3可以有效抑制活性物质的团聚并提高复合电极的电导率。

更新日期:2018-07-12
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