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Synthesis, crystal structure, and 19F, 1H NMR investigation of the first compound of indium(III) with an amino acid
Journal of Fluorine Chemistry ( IF 1.9 ) Pub Date : 2018-05-17 , DOI: 10.1016/j.jfluchem.2018.05.006
V.Ya. Kavun , R.L. Davidovich , A.A. Udovenko , M.M. Polyantsev , V.B. Logvinova

The first compound of indium(III) with an amino acid – triglycinium hexafluoridoindate(III), (C2H6NO2)3[InF6] – was synthesized and investigated by X-ray, and 19F, 1H NMR methods. The structure of (C2H6NO2)3[InF6] is formed by slightly distorted octahedral complex [InF6]3– anions and protonated glycinium cations (C2H6NO2)+, which are linked by hydrogen bonds into a three-dimensional framework. The character of ionic motions in fluoride and proton sublattices upon temperature variation has been examined, and their types and temperature ranges, within which they are realized, have been determined.



中文翻译:

铟(III)的第一种化合物与氨基酸的合成,晶体结构和19 F,1 H NMR研究

合成了第一个具有氨基酸的铟(III)化合物-六氟亚氨酸三甘氨酸(III)(C 2 H 6 NO 23 [InF 6 ] –并通过X射线和19 F,1 H NMR方法进行了研究。 。(C 2 H 6 NO 23 [InF 6 ]的结构是由略微扭曲的八面体络合物[InF 6 ] 3–阴离子和质子化的糖化阳离子(C 2 H 6 NO 2+形成的。,它们通过氢键连接成三维框架。考察了随着温度变化氟化物和质子亚晶格中离子运动的特性,并确定了它们的类型和温度范围。

更新日期:2018-05-17
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