AbstractThis focus review addresses recent progress on plant oil-based functional polymers and composites. Plant oils are one of the most ideal chemical feedstocks to replace fossil resources for a variety of industrial chemicals in the polymer industry. In this focus review, an environmentally benign coating system is demonstrated using plant oils as the starting substrate for the preparation of artificial urushi with high hardness and a high gloss surface. Epoxidized plant oils, mainly epoxidized soybean oil, are polymerized with designed inorganics, cellulose, and biodegradable aliphatic polyesters to afford functional biobased polymers and composites. Castor oil is used as the core of branched poly(lactic acid) to improve the physical properties of biobased plastics. These plant oil-based materials are significant for the molecular design of functional and high-performance biobased products for industrial applications to contribute to the reduction of greenhouse emissions.This focus review addresses recent progress on plant oil-based functional polymers and composites. An environmentally benign coating system is demonstrated using plant oils as the starting substrate for the preparation of artificial urushi with high hardness and a high gloss surface. Epoxidized plant oils are polymerized with designed inorganics, cellulose, and biodegradable aliphatic polyesters to afford functional biobased polymers and composites. Castor oil is used as the core of branched poly(lactic acid) to improve the physical properties of biobased plastics.

中文翻译：

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来自可再生植物油的功能性聚合物

摘要本综述重点介绍了植物油基功能聚合物和复合材料的最新进展。植物油是最理想的化学原料之一，可替代聚合物工业中各种工业化学品的化石资源。在本次重点审查中，展示了使用植物油作为制备高硬度和高光泽表面人造漆的起始基材的环境友好型涂料系统。环氧化植物油，主要是环氧化大豆油，与设计的无机物、纤维素和可生物降解的脂肪族聚酯聚合，以提供功能性生物基聚合物和复合材料。蓖麻油用作支化聚乳酸的核心，以改善生物基塑料的物理性能。这些植物油基材料对于工业应用的功能性和高性能生物基产品的分子设计具有重要意义，有助于减少温室气体排放。本综述重点介绍了植物油基功能聚合物和复合材料的最新进展。使用植物油作为制备具有高硬度和高光泽表面的人造漆的起始基材，展示了一种环境友好的涂层系统。环氧化植物油与设计的无机物、纤维素和可生物降解的脂肪族聚酯聚合，以提供功能性生物基聚合物和复合材料。蓖麻油用作支化聚乳酸的核心，以改善生物基塑料的物理性能。使用植物油作为制备具有高硬度和高光泽表面的人造漆的起始基材，展示了一种环境友好的涂层系统。环氧化植物油与设计的无机物、纤维素和可生物降解的脂肪族聚酯聚合，以提供功能性生物基聚合物和复合材料。蓖麻油用作支化聚乳酸的核心，以改善生物基塑料的物理性能。使用植物油作为制备具有高硬度和高光泽表面的人造漆的起始基材，展示了一种环境友好的涂层系统。环氧化植物油与设计的无机物、纤维素和可生物降解的脂肪族聚酯聚合，以提供功能性生物基聚合物和复合材料。蓖麻油用作支化聚乳酸的核心，以改善生物基塑料的物理性能。