Rhodium‐Catalyzed Synthesis of Dialkyl(Heteroaryl)Phosphine Sulfides by Phosphinylation of Heteroaryl Sulfides,Advanced Synthesis & Catalysis

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Rhodium‐Catalyzed Synthesis of Dialkyl(Heteroaryl)Phosphine Sulfides by Phosphinylation of Heteroaryl Sulfides
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-08-02 , DOI: 10.1002/adsc.201800630
Mieko Arisawa ₁ , Takeru Tazawa ₁ , Wataru Ichinose ₁ , Haruki Kobayashi ₁ , Masahiko Yamaguchi ₁

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Dialkyl(heteroaryl)phosphine sulfides were synthesized by the rhodium‐catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl)phosphine sulfides containing five‐ and six‐membered heteroaryl groups. Various dialkyl(heteroaryl)phosphines were obtained by desulfurization.

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