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Oxidation of Tertiary Aromatic Alcohols to Ketones in Water
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2018-08-03 , DOI: 10.1002/adsc.201800612
Dengfeng Chen 1 , Yuchen Zhang 1 , Xingyu Pan 2 , Fei Wang 1 , Shenlin Huang 1
Affiliation  

A new rosin‐based amphiphile enables the oxidation of tertiary aromatic alcohols in water under mild conditions. The oxidation process is mediated by β‐scission of alkoxy radicals. Our catalyst system including the surfactant, catalysts, and water can be easily recycled within the same reaction vial.

中文翻译:

叔芳香醇在水中被氧化成酮

一种新的基于松香的两亲物能够在温和条件下氧化水中的芳族叔醇。氧化过程是由烷氧基的β断裂介导的。我们的催化剂体系,包括表面活性剂,催化剂和水,可以在同一反应瓶中轻松回收。
更新日期:2018-08-03
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