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NaI-mediated divergent synthesis of isatins and isoindigoes: a new protocol enabled by an oxidation relay strategy†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-07-04 00:00:00 , DOI: 10.1039/c8cc04471f
Hong-hua Zhang 1, 2, 3, 4 , Yong-qiang Wang 1, 2, 3, 4 , Long-tao Huang 1, 2, 3, 4 , Long-qing Zhu 1, 2, 3, 4 , Yi-yue Feng 1, 2, 3, 4 , Ying-mei Lu 1, 2, 3, 4 , Quan-yi Zhao 1, 2, 3, 4 , Xue-qiang Wang 4, 5, 6, 7, 8 , Zhen Wang 1, 2, 3, 4
Affiliation  

A new approach for the synthesis of isatins and isoindigoes by an inexpensive and environmentally friendly NaI-mediated transformation is disclosed. The selectivity could be switched by simply varying the solvent, and isatins (using THF) and isoindigoes (using DMSO) could be obtained in moderate to excellent yields.

中文翻译:

NaI介导的靛红和异靛蓝的发散性合成:通过氧化中继策略实现的新协议

公开了一种通过廉价且环境友好的NaI介导的转化合成靛红和异靛蓝的新方法。可以通过简单地改变溶剂来切换选择性,并且可以中等至极好的收率获得靛红(使用THF)和异靛蓝(使用DMSO)。
更新日期:2018-07-04
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