当前位置: X-MOL 学术Tetrahedron Lett. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Synthesis of unsaturated silyl nitronates via the silylation of conjugated nitroalkenes
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-07-03 , DOI: 10.1016/j.tetlet.2018.07.011
Elizaveta A. Khotyantseva , Andrey A. Tabolin , Roman A. Novikov , Yulia V. Nelyubina , Sema L. Ioffe

A new method for the synthesis of conjugated silyl nitronates from nitroalkenes is described. The procedure has wide substrate scope and is compatible with in situ generation of the substrates from 2-nitroalcohols or 2-chloro-nitroalkanes. A cascade transformation to give 3,4,5,6-tetrahydropyridine N-oxide derivatives was disclosed.



中文翻译:

通过共轭硝基烯烃的甲硅烷基化反应合成不饱和甲硅烷基磺酸盐

描述了一种从硝基烯烃合成共轭硅烷基磺酸盐的新方法。该方法具有广泛的底物范围,并且与由2-硝基醇或2-氯-硝基烷烃原位生成底​​物兼容。公开了一种级联转化,得到3,4,5,6-四氢吡啶N-氧化物衍生物。

更新日期:2018-07-03
down
wechat
bug