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Sweet graphene: exfoliation of graphite and preparation of glucose-graphene cocrystals through mechanochemical treatments
Green Chemistry ( IF 9.8 ) Pub Date : 2018-07-02 , DOI: 10.1039/c8gc01162a
Viviana Jehová González 1, 2, 3, 4 , Antonio M. Rodríguez 1, 2, 3, 4, 5 , Verónica León 1, 2, 3, 4 , Javier Frontiñán-Rubio 1, 2, 3, 4, 6 , José Luis G. Fierro 4, 7, 8, 9, 10 , Mario Durán-Prado 4, 6, 11, 12, 13 , Ana B. Muñoz-García 14, 15, 16, 17 , Michele Pavone 5, 15, 16, 17 , Ester Vázquez 1, 2, 3, 4, 18
Affiliation  

Mechanochemical treatment with carbohydrates leads to the successful exfoliation of graphite and this can be considered as a green approach to the preparation of graphene. Glucose, fructose and saccharose were used and the former showed the best exfoliation behaviour to generate graphene materials with a relatively low number of defects, as evidenced by Raman spectroscopy. The addition of small amounts of water to the ball milling treatment led to the formation of glucose-graphene co-crystals, which exhibited superior properties in terms of colloidal stability and minimization of cell toxicity.

中文翻译:

甜石墨烯:通过机械化学处理剥落石墨并制备葡萄糖-石墨烯共晶体

用碳水化合物进行机械化学处理可成功剥落石墨,这可以认为是制备石墨烯的绿色方法。使用了葡萄糖,果糖和蔗糖,前者表现出最佳的剥落性能,可产生缺陷数量相对较少的石墨烯材料,拉曼光谱法证明了这一点。在球磨处理中添加少量水导致形成葡萄糖-石墨烯共晶体,就胶体稳定性和最小化细胞毒性而言,它们表现出优异的性能。
更新日期:2018-07-30
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