Transition Metal‐Catalyzed C−H Bond Functionalizations by Use of Sulfur‐Containing Directing Groups,Advanced Synthesis & Catalysis

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Transition Metal‐Catalyzed C−H Bond Functionalizations by Use of Sulfur‐Containing Directing Groups
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-10-09 , DOI: 10.1002/adsc.201800484
Kai‐Xiang Tang ₁ , Chun‐Meng Wang ₁ , Tian‐Hong Gao ₁ , Lin Chen ₁ , Lian Fan ₁ , Li‐Ping Sun ₁

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Transition metal‐catalyzed direct functionalization of C−H bonds is an economical and efficient way to construct complex molecules that is currently attracting tremendous attention. In particular, the strategy involving transition metal‐catalyzed regioselective C−H activation assisted by sulfur‐containing directing groups has been realized in the past few years in spite of sulfur's ability to poison many transition metal catalysts. This review describes the rational development of sulfur‐containing directing groups including thioethers, sulfoxides, thioamides, alkoxythiocarbonyl groups, and thioketones. Through collective efforts in the community, a range of transition metal‐catalyzed C−H activation transformations using this type of directing group has been developed.

中文翻译：

过渡金属催化的CH键通过使用含硫的导向基团进行官能化

过渡金属催化的CH键的直接官能化是一种经济有效的方法来构建复杂的分子，目前引起了极大的关注。尤其是，尽管硫磺能够使许多过渡金属催化剂中毒，但在过去几年中已经实现了涉及由含硫的导向基团协助的过渡金属催化的区域选择性C-H活化的策略。这篇综述描述了含硫指导基团的合理发展，包括硫醚，亚砜，硫代酰胺，烷氧基硫代羰基和硫代酮。通过社区的集体努力，已经开发出了一系列使用这种类型的导向基团的过渡金属催化的CH活化转化。

更新日期：2018-10-09

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