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Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2018-07-01 , DOI: 10.1021/jacs.8b03302
Michael J. James 1 , Jonas Luca Schwarz 1 , Felix Strieth-Kalthoff 1 , Birgit Wibbeling 1 , Frank Glorius 1
Affiliation  

The discovery and application of dearomative cascade photocatalysis as a strategy in complex molecule synthesis is described. Visible-light-absorbing photosensitizers were used to (sequentially) activate a 1-naphthol derived arene precursor to divergently form two different polycyclic molecular scaffolds through catalyst selective energy transfer.

中文翻译:

脱芳级联光催化:通过催化剂选择性能量转移的发散合成

描述了脱芳基级联光催化作为复杂分子合成策略的发现和应用。可见光吸收光敏剂用于(依次)激活 1-萘酚衍生的芳烃前体,通过催化剂选择性能量转移发散形成两种不同的多环分子支架。
更新日期:2018-07-01
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