Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2018-06-25 , DOI: 10.1016/j.jssc.2018.06.027 Ying Zhou , Chuanchuan Gu , Xuliang Chen , Yonghui Zhou , Chao An , Zhaorong Yang
We performed in situ high-pressure synchrotron x-ray diffraction (XRD) and electrical transport measurements on topological semimetal TaSb2 in diamond anvil cells with pressures up to 60.0–63.0 GPa. No evident trace of structural phase transitions is observed from our XRD. A fit of the volume versus pressure data by using the third-order Birch–Murnaghan equation of state yields the bulk modulus = 131.2 ± 3.4 GPa and its first-order derivative = 6 ± 0.3. From ambient pressure to 27.8 GPa, the low-temperature conduction behaviors of TaSb2 stay almost unchanged, exhibiting a power law with the exponent around 3; meanwhile, the magnetoresistance (MR) at 5 K follows a same relationship of MR∝Bm with m= 1.45 ± 0.10. These results imply that the topological semimetal state of TaSb2 may be robust subjected to pressure, at least to 27.8 GPa.
中文翻译:
高压下拓扑半金属TaSb 2的结构和输运性质
我们对压力高达60.0-63.0 GPa的金刚石砧室中的拓扑半金属TaSb 2进行了原位高压同步加速器X射线衍射(XRD)和电迁移测量。从我们的XRD中没有观察到明显的结构相变痕迹。通过使用三阶Birch-Murnaghan状态方程拟合体积与压力的关系,可以得出体积模量= 131.2±3.4 GPa及其一阶导数 = 6±0.3。从环境压力到27.8 GPa,TaSb 2的低温传导行为几乎保持不变,表现出幂律,指数在3左右。同时,在5 K时的磁阻(MR)遵循MR ∝ B m的相同关系,其中m = 1.45±0.10。这些结果表明,TaSb 2的拓扑半金属态在至少27.8 GPa的压力下会很坚固。