Cu2O/TiO2 nanoparticles as visible light photocatalysts concerning C(sp2)–P bond formation†,Catalysis Science & Technology

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Cu2O/TiO2 nanoparticles as visible light photocatalysts concerning C(sp2)–P bond formation†
Catalysis Science & Technology ( IF 4.4 ) Pub Date : 2018-06-28 00:00:00 , DOI: 10.1039/c8cy00822a
Mona Hosseini-Sarvari _{1,

2,

3,

4,

5} , Fattaneh Jafari _{1,

2,

3,

4,

5} , Afshan Mohajeri _{1,

2,

3,

4,

5} , Nasim Hassani _{1,

2,

3,

4,

5}

Affiliation

A novel and efficient method has been developed for the construction of an aromatic-phosphorus (Ar-P) bond under visible light irradiation using Cu₂O/TiO₂ nanoparticles as inexpensive and available photocatalysts. This protocol is a simple system without the use of any base, ligand, oxidant, or special conditions. This is the first report for the synthesis of arylphosphonates from arylhydrazines in visible light irradiation.

中文翻译：

Cu ₂ O / TiO ₂纳米颗粒作为涉及C（sp ²）-P键形成的可见光催化剂†

已经开发出一种新颖有效的方法，用于在可见光照射下使用Cu ₂ O / TiO ₂纳米粒子作为廉价和可用的光催化剂来构建芳族磷（Ar-P）键。该方案是一个简单的系统，无需使用任何碱，配体，氧化剂或特殊条件。这是在可见光照射下由芳基肼合成芳基膦酸酯的第一份报告。

更新日期：2018-06-28

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