Sulfur-doped BiOCl (BiOCl-S) photocatalysts were synthesized using a simple and effective method. The as-synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman scattering spectroscopy, photoluminescence (PL) spectroscopy and ultraviolet visible (UV-vis) absorption spectroscopy. During the photodegradation of rhodamine B under visible light shows, BiOCl-S exhibits higher activity than BiOCl. Sn, Mn doped BiOCl were also synthesized successfully with the same doping route. We provide a simple and effective method for the element doping of bismuth oxyhalides. BiOCl-S photocatalyst may be one of the promising materials for the degradation of organic environmental pollution.

使用简单有效的方法合成了硫掺杂的BiOCl（BiOCl-S）光催化剂。合成后的样品通过X射线衍射（XRD），扫描电子显微镜（SEM），拉曼散射光谱，光致发光（PL）光谱和紫外可见（UV-vis）吸收光谱进行表征。在可见光下若丹明B的光降解过程中，BiOCl-S表现出比BiOCl更高的活性。还以相同的掺杂路线成功地合成了Sn，Mn掺杂的BiOCl。我们提供了一种简单而有效的方法来掺杂卤氧化铋。BiOCl-S光催化剂可能是降解有机环境污染的有前途的材料之一。