Continuum of covalent to intermolecular bonding in the halogen-bonded complexes of 1,4-diazabicyclo[2.2.2]octane with bromine-containing electrophiles†,Chemical Communications

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Continuum of covalent to intermolecular bonding in the halogen-bonded complexes of 1,4-diazabicyclo[2.2.2]octane with bromine-containing electrophiles†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-06-27 00:00:00 , DOI: 10.1039/c8cc04629h
Craig Weinberger _{1,

2,

3,

4} , Rachel Hines _{1,

2,

3,

4} , Matthias Zeller _{1,

4,

5,

6} , Sergiy V. Rosokha _{1,

2,

3,

4}

Affiliation

A gradual change of Br⋯N bond lengths and strengths from the values typical for intermolecular associates to that characteristic of a covalent bond was observed in a series of halogen-bonded complexes. This continuum reveals a fundamental relationship between the limiting types of bonding and implies the onset of covalency in the intermolecular interactions.

更新日期：2018-06-27

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