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Oxygen-deficient bismuth tungstate and bismuth oxide composite photoanode with improved photostability
Science Bulletin ( IF 18.8 ) Pub Date : 2018-06-27 , DOI: 10.1016/j.scib.2018.06.012
Hoi Ying Chung 1 , Weijian Chen 2 , Xiaoming Wen 3 , Judy N Hart 4 , Hao Wu 1 , Yuekun Lai 5 , Rose Amal 1 , Yun Hau Ng 1
Affiliation  

A homogeneous layer of Bi2O3-Bi14WO24 composite (BWO/Bi2O3) thin film was fabricated using a combination of electrodeposition and thermal treatment. The evenly distributed Bi14WO24 component within the Bi2O3 layer was found to be important in stabilising the photoelectrochemical performances of Bi2O3 photoanode by promoting the photoelectron transport. The unmodified Bi2O3 suffered from severe photocorrosion as proven by X-ray diffraction (XRD) and inductively coupled plasma (ICP) analyses while the composite thin film was active without noticeable activity decay for at least 3 h of illumination. This strategy might be applicable to other photocatalysts with stability issues.



中文翻译:

光稳定性提高的缺氧钨酸铋和氧化铋复合光阳极

Bi 2 O 3 -Bi 14 WO 24复合材料 (BWO/Bi 2 O 3 ) 薄膜的均匀层是使用电沉积和热处理的组合制造的。发现在 Bi 2 O 3层内均匀分布的 Bi 14 WO 24组分通过促进光电子传输对于稳定 Bi 2 O 3光阳极的光电化学性能很重要。未改性的 Bi 2 O 3通过 X 射线衍射 (XRD) 和电感耦合等离子体 (ICP) 分析证明,复合薄膜在至少 3 小时的光照下没有明显的活性衰减。该策略可能适用于其他存在稳定性问题的光催化剂。

更新日期:2018-06-27
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