Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide†,Organic Chemistry Frontiers

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Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide†
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2018-06-22 00:00:00 , DOI: 10.1039/c8qo00507a
Ke-Jin Jiao _{1,

2,

3,

4,

5} , Zhao-Ming Li _{1,

2,

3,

4,

5} , Xue-Tao Xu _{6,

7,

8,

9} , Li-Pu Zhang _{6,

7,

8,

9} , Yi-Qian Li _{6,

7,

8,

9} , Kun Zhang _{6,

7,

8,

9} , Tian-Sheng Mei _{1,

2,

3,

4,

5}

Affiliation

Palladium-catalyzed regioselective electrocarboxylation of homostyrenyl acetates with CO₂ has been successfully developed, providing α-aryl carboxylic acids with good selectivity and yield. In addition, the catalytic asymmetric carboxylation of cinnamyl acetate has been demonstrated, despite moderate enantioselectivity.

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