Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes†‡,Dalton Transactions

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Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes†‡
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-06-22 00:00:00 , DOI: 10.1039/c8dt01875h
Michael A. Land _{1,

2,

3,

4,

5} , Bright Huo _{1,

2,

3,

4,

5} , Katherine N. Robertson _{1,

2,

3,

4,

5} , Kai E. O. Ylijoki _{1,

2,

3,

4,

5} , Peter T. K. Lee _{1,

2,

3,

4,

5} , Jetsuda Areephong _{1,

2,

3,

4,

5} , Dragoslav Vidović _{6,

7,

8,

9} , Jason A. C. Clyburne _{1,

2,

3,

4,

5}

Affiliation

In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N’-bis(p-tolyl)propanediimidate. Their corresponding rhodium(I) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N’-chelating ligand nacnac.

中文翻译：

富电子的乙氧基和二甲基氨基取代的1,3-二酮化配体及其配合物的配位，反应性和结构性质† ‡

在本文中我们描述了合成，表征，和两个配体，二乙基-的X射线晶体结构Ñ，Ñ双（p -甲苯基）malonimidate和1,3-双（二甲基氨基） - ñ，N” -双（对甲苯基）丙二亚胺。还制备并表征了它们相应的二羰基铑（I），二甲基铝和双连接的锌络合物。已经研究了配体的供体性质，并将其与传统的阴离子N，N'-螯合配体nacnac进行了比较。

更新日期：2018-06-22

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