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An Insight into Adaptive Deformation of Rigid Cucurbit[6]uril Host in Symmetric [2]Pseudorotaxanes
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-08-16 , DOI: 10.1002/ejoc.201800964
Fei-ze Li 1, 2 , Lei Mei 2 , Qun-yan Wu 2 , Yin Tian 3 , Kong-qiu Hu 2 , Yun-chen Ge 2 , Ning Liu 1 , John K. Gibson 4 , Zhi-fang Chai 2 , Wei-qun Shi 2
Affiliation  

Adaptive deformation of rigid CB[6]: Structural deformation of rigid CB[6] is observed after inclusion of ill‐suited flexible homologous bipyridinium guests in [2]pseudorotaxane, which is attributed as an adaptive response of the macrocyclic host to guests of different sizes for making up the weak host–guest binding affinity.
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中文翻译:

对称[2]假轮烷中刚性葫芦[6] uril宿主的自适应变形的见解

刚性CB [6]的自适应变形:在[2]假轮烷中包含不合适的柔性同源联吡啶鎓客体后,观察到刚性CB [6]的结构变形,这归因于大环主体对不同客体的自适应响应组成弱宿主-客体结合亲和力的大小。
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更新日期:2018-08-16
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