Triboelectric nanogenerators (TENGs), which have demonstrated that all moving things in the universe can generate electricity in a sustainable way are currently being developed to be integrated with electronics, and to improve user convenience. The electrically charged surface upon a contact electrification phenomenon caused by contact of the materials determines the output performance of TENGs. This review focuses on the electrification and surface charge density characteristics of various fluoropolymer-based materials as active materials that have been investigated to realize high performance TENGs, and the results of the study of their applications. Furthermore, the characteristics of electrification with differently polymerized P(VDF-TrFE) as TENGs’ active materials and their applications are reviewed. The boosted output performance characteristics when used as a matrix material and integrated with a composite system with a high dielectric constant material are also reviewed. Finally, the paper presents three perspectives on the direction of TENG research for future improvement, namely material, structure, and circuitry.

摩擦电纳米发电机（TENGs）已经证明，宇宙中所有移动的事物都可以可持续方式发电，目前正在开发该技术与电子技术集成在一起，以提高用户的便利性。由材料接触引起的接触带电现象产生的带电表面决定了TENG的输出性能。这篇综述着重于各种含氟聚合物基材料作为活性材料的带电和表面电荷密度特性，这些材料已被研究以实现高性能的TENGs，以及它们的应用研究结果。此外，还综述了以不同聚合的P（VDF-TrFE）作为TENGs的活性材料的带电特性及其应用。当用作基体材料并与具有高介电常数材料的复合系统集成时，还可以提高输出性能。最后，本文提出了关于TENG未来发展方向的三种观点，即材料，结构和电路。