A Protocol for Direct Stereospecific Amination of Primary, Secondary, and Tertiary Alkylboronic Esters,Synlett

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A Protocol for Direct Stereospecific Amination of Primary, Secondary, and Tertiary Alkylboronic Esters
Synlett ( IF 1.7 ) Pub Date : 2018-06-20 , DOI: 10.1055/s-0037-1610172
James Morken ₁ , Emma Edelstein ₁ , Andrea Grote ₁ , Maximilian Palkowitz ₁

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The direct, stereospecific amination of alkylboronic and borinic esters can be conducted by treatment of the organoboron compound with methoxyamine and potassium tert-butoxide. In addition to being stereospecific, this process also enables the direct amination of tertiary boronic esters in an efficient fashion.

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