Visible-light-enabled oxyazidation of alkenes leading to α-azidoketones in air,Green Chemistry

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Visible-light-enabled oxyazidation of alkenes leading to α-azidoketones in air
Green Chemistry ( IF 9.3 ) Pub Date : 2018-06-21 , DOI: 10.1039/c8gc01245h
Wei Wei _{1,

2,

3,

4,

5} , Huanhuan Cui _{6,

7,

8,

9} , Huilan Yue _{9,

10,

11,

12,

13} , Daoshan Yang _{1,

2,

3,

4,

5}

Affiliation

A new and facile visible-light-enabled method for the synthesis of α-azidoketones has been developed via oxyazidation of alkenes with TMSN₃ in air at room temperature. A series of α-azidoketones could be easily and efficiently obtained in moderate to excellent yields via cascade C–N and C [double bond, length as m-dash]