An exploration of the use of Au submonolayer decorated Pd7Ir nanoparticles as a highly active electrocatalyst for the ethanol oxidation reaction in alkaline media†,Catalysis Science & Technology

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An exploration of the use of Au submonolayer decorated Pd7Ir nanoparticles as a highly active electrocatalyst for the ethanol oxidation reaction in alkaline media†
Catalysis Science & Technology ( IF 4.4 ) Pub Date : 2018-06-21 00:00:00 , DOI: 10.1039/c8cy01176a
Shuiyun Shen _{1,

2,

3,

4,

5} , Yangge Guo _{1,

2,

3,

4,

5} , Guanghua Wei _{4,

5,

6,

7} , Liuxuan Luo _{1,

2,

3,

4,

5} , Fan Li _{1,

2,

3,

4,

5} , Lin Li _{1,

2,

3,

4,

5} , Guofeng Xia _{1,

2,

3,

4,

5} , Junliang Zhang _{1,

2,

3,

4,

5}

Affiliation

Although very promising in its stabilizing effect, an inevitable loss on activity mostly exists when combining gold (Au) with other noble metals. Contrary to this knowledge, in this research an unexpected promotion of the Au submonolayer on palladium-iridium/carbon (Pd₇Ir/C) nanoparticles towards the ethanol oxidation reaction in alkaline media was explored and the corresponding mechanism was clarified.

中文翻译：

探索使用Au亚单层修饰的Pd ₇ Ir纳米颗粒作为碱性介质中乙醇氧化反应的高活性电催化剂†

尽管其稳定作用非常有前途，但在将金（Au）与其他贵金属结合使用时，大多数情况下会不可避免地降低活性。与该知识相反，在这项研究中，探索了钯-铱/碳（Pd ₇ Ir / C）纳米粒子上的Au亚单层对碱性介质中乙醇氧化反应的意外促进，并阐明了相应的机理。

更新日期：2018-06-21

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