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Cleave and couple: toward fully sustainable catalytic conversion of lignocellulose to value added building blocks and fuels
Chemical Communications ( IF 4.3 ) Pub Date : 2018-06-21 , DOI: 10.1039/c8cc02937g Zhuohua Sun 1, 2, 3, 4 , Katalin Barta 1, 2, 3, 4
Chemical Communications ( IF 4.3 ) Pub Date : 2018-06-21 , DOI: 10.1039/c8cc02937g Zhuohua Sun 1, 2, 3, 4 , Katalin Barta 1, 2, 3, 4
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The structural complexity of lignocellulose offers unique opportunities for the development of entirely new, energy efficient and waste-free pathways in order to obtain valuable bio-based building blocks. Such sustainable catalytic methods – specifically tailored to address the efficient conversion of abundant renewable starting materials – are necessary to successfully compete, in the future, with fossil-based multi-step processes. In this contribution we give a summary of recent developments in this field and describe our “cleave and couple” strategy, where “cleave” refers to the catalytic deconstruction of lignocellulose to aromatic and aliphatic alcohol intermediates, and “couple” involves the development of novel, sustainable transformations for the formation of C–C and C–N bonds in order to obtain a range of attractive products from lignocellulose.
中文翻译：
劈裂并耦合：实现木质纤维素完全可持续的催化转化为增值构建基块和燃料
木质纤维素的结构复杂性为开发全新的，节能且无浪费的途径提供了独特的机会，以便获得有价值的基于生物的构件。这种可持续的催化方法（专门为解决丰富的可再生原料的有效转化而专门设计）对于将来与基于化石的多步工艺成功竞争是必不可少的。在这篇文章中，我们总结了该领域的最新进展，并描述了我们的“裂解和偶联”策略，其中“裂解”是指木质纤维素催化分解为芳族和脂族醇中间体，而“偶联”涉及新型的开发。 ，
更新日期：2018-06-22
中文翻译：
劈裂并耦合：实现木质纤维素完全可持续的催化转化为增值构建基块和燃料
木质纤维素的结构复杂性为开发全新的，节能且无浪费的途径提供了独特的机会，以便获得有价值的基于生物的构件。这种可持续的催化方法（专门为解决丰富的可再生原料的有效转化而专门设计）对于将来与基于化石的多步工艺成功竞争是必不可少的。在这篇文章中，我们总结了该领域的最新进展，并描述了我们的“裂解和偶联”策略，其中“裂解”是指木质纤维素催化分解为芳族和脂族醇中间体，而“偶联”涉及新型的开发。 ，
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