Remote Control of Anion–π Catalysis on Fullerene‐Centered Catalytic Triads,Angewandte Chemie International Edition

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Remote Control of Anion–π Catalysis on Fullerene‐Centered Catalytic Triads
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-06-21 , DOI: 10.1002/anie.201806824
Javier López-Andarias ₁ , Antonio Bauzá ₂ , Naomi Sakai ₁ , Antonio Frontera ₂ , Stefan Matile ₁

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Remote catalytic control in fullerene‐centered triads leads to the highest activity in anion–π catalysis observed so far. Using an enolate addition benchmark reaction, A. Frontera, S. Matile, and co‐workers demonstrated in their Communication (DOI: 10.1002/anie.201804092) the importance of dynamic contributions, i.e. from polarizability‐dependent anion‐induced dipoles, which exceed that of static contributions to anion–π interactions by far.

中文翻译：

以富勒烯为中心的催化三元体系对阴离子-π催化的远程控制

到目前为止，在以富勒烯为中心的三单元组中进行远程催化控制可导致阴离子-π催化活性最高。A. Frontera，S。Matile和他的同事使用烯醇酸加成基准反应，在他们的交流中（DOI：10.1002 / anie.201804092）证明了动态贡献的重要性，即来自极化率依赖性阴离子诱导的偶极子的贡献超过到目前为止对阴离子-π相互作用的静态贡献。

更新日期：2018-06-22

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