Core–Shell Crystals of Porous Organic Cages,Angewandte Chemie International Edition

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Core–Shell Crystals of Porous Organic Cages
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-06-21 , DOI: 10.1002/anie.201806818
Shan Jiang ₁ , Yi Du ₂ , Marco Marcello ₃ , Edward W. Corcoran ₂ , David C. Calabro ₂ , Samantha Y. Chong ₁ , Linjiang Chen ₁ , Rob Clowes ₁ , Tom Hasell ₁ , Andrew I. Cooper ₁

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Core–shell crystals of porous materials allow multiple functionalities to be used synergistically, for example choosing the core material for capacity, and the shell for selectivity, or surface properties. The few previous examples have all been based on frameworks, but in this Communication (DOI: 10.1002/anie.201803244), T. Hasell, A. I. Cooper et al. present the first report of core–shell crystals formed from porous molecules, in this case porous organic cages—which are directed by chiral recognition. Depicted are octahedral crystals with a fluorescent cage as the core, and a non‐fluorescent cage shell layer growing on the surface.

中文翻译：

多孔有机笼的核-壳晶体

多孔材料的核-壳晶体允许协同使用多种功能，例如，选择核材料以获得容量，选择壳以获得选择性或表面特性。前面的几个示例都基于框架，但在本交流中（DOI：10.1002 / anie.201803244），T。Hasell，A。I. Cooper等人。首次报道了由多孔分子（在这种情况下为多孔有机笼）形成的核-壳晶体，这些分子是通过手性识别来控制的。描绘的是八面体晶体，其中荧光笼为核心，并且在表面生长有非荧光笼壳层。

更新日期：2018-06-22

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