Efficient hydroboration of carbonyls by an iron(ii) amide catalyst†,Dalton Transactions

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Efficient hydroboration of carbonyls by an iron(ii) amide catalyst†
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-06-20 00:00:00 , DOI: 10.1039/c8dt01998c
Ashim Baishya _{1,

2,

3,

4} , Swavalina Baruah _{1,

2,

3,

4} , K. Geetharani _{1,

2,

3,

4}

Affiliation

An easily prepared iron(II) amide precatalyst enables the selective hydroboration of carbonyls with HBpin (pinacolborane) in the absence of any additive. The reactions proceed with low catalytic loading (1–3 mol%) under mild reaction conditions and display wide functional group compatibility. Aldehydes are selectively hydroborated in the presence of other reducible functional groups, such as ketones, alkenes, nitriles, esters, amides, acids and halides.

中文翻译：

铁（ii）酰胺催化剂对羰基进行有效的硼氢化反应†

易于制备的铁（II）酰胺铁预催化剂可在不添加任何添加剂的情况下，用HBpin（频哪硼烷）对羰基进行选择性氢硼化。在温和的反应条件下，反应以较低的催化负荷（1-3 mol％）进行，并显示出广泛的官能团相容性。在其他可还原的官能团（例如酮，烯烃，腈，酯，酰胺，酸和卤化物）的存在下，醛被选择性氢硼化。

更新日期：2018-06-20

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