Lewis-Base-Induced Disproportionation of a Dialane.,Chemistry - A European Journal

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Lewis-Base-Induced Disproportionation of a Dialane.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-07-18 , DOI: 10.1002/chem.201802300
Alexander Hofmann ₁ , Anna Lamprecht ₁ , J Oscar C Jiménez-Halla ₂ , Tobias Tröster ₁ , Rian D Dewhurst ₁ , Carsten Lenczyk ₁ , Holger Braunschweig ₁

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The reaction of a pentamethylcyclopentadienyl‐substituted dialane with a variety of Lewis bases results in unexpected disproportionation of the dialane into Al^I and Al^III species. Use of a transition‐metal Lewis base allows for the formation of metal‐only Lewis pairs. Furthermore, the synthesis of a Lewis base bis‐adduct was successful with the Lewis base 4‐dimethylaminopyridine.

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