Syntheses, Structures and Dynamics of 9‐(Ferrocenylmethyl)anthracene and Related Molecular Gears: Phosphorus to the Rescue!,European Journal of Organic Chemistry

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Syntheses, Structures and Dynamics of 9‐(Ferrocenylmethyl)anthracene and Related Molecular Gears: Phosphorus to the Rescue!
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2018-08-17 , DOI: 10.1002/ejoc.201800938
Kirill Nikitin ₁ , Yannick Ortin ₁ , Helge Müller-Bunz ₁ , Declan G. Gilheany ₁ , Michael J. McGlinchey ₁

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Conventional reduction of 9‐ferrocenoylanthracene yields only the corresponding dihydroanthracene. In contrast, deoxygenation of (9‐anthracenyl)(ferrocenyl)methanol to form 9‐(ferrocenylmethyl)anthracene proceeds efficiently upon treatment with triphenylphosphine/triflic acid, and subsequent hydrolysis.