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Investigation of uranium (VI) adsorption by poly(dopamine) functionalized waste paper derived carbon
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-06-19 , DOI: 10.1016/j.jtice.2018.05.024
Jiahui Zhu , Qi Liu , Jingyuan Liu , Rongrong Chen , Hongsen Zhang , Milin Zhang , Peili Liu , Rumin Li , Jun Wang

Waste paper derived carbon coated with poly(dopamine) ([email protected]) as a novel adsorbent was synthesized successfully by activation of KOH and carbonization of waste A4 paper, followed by in situ polymerization of dopamine. [email protected] composites possessed a 3D hierarchically interconnected porous structure and the Brunauer–Emmett–Teller (BET) specific surface area is calculated to be 364.6 m2/g. The enrichment of uranium for [email protected] composites from not only aqueous solution (mg/L) but also simulated seawater (μg/L) was fully evaluated under different scenarios. The experimental results indicated the maximum absorption capacity to uranium (VI) of [email protected] composites was 384.6 mg/g at pH 7. In addition, the distribution coefficient (Kd) of U (VI) ion with other competing ions for [email protected] composites is 1.97 × 104 mg/L and demonstrated excellent selectivity to uranium (VI) in simulated seawater, which augurs well for the application of the adsorbent in seawater.



中文翻译:

聚多巴胺功能化废纸衍生碳吸附铀的研究

通过KOH的活化和废A4纸的碳化,然后原位聚合多巴胺,成功地合成了废纸衍生的碳,该纸涂覆有聚(多巴胺)([电子邮件保护])作为新型吸附剂。[受电子邮件保护]复合材料具有3D层次结构互连的多孔结构,Brunauer-Emmett-Teller(BET)的比表面积经计算为364.6 m 2 / g。在不同情况下,不仅从水溶液(mg / L)而且从模拟海水(μg/ L)中对[受电子邮件保护的]复合材料中铀的富集进行了全面评估。实验结果表明,[电子邮件保护的]复合材料在pH值为7时对铀(VI)的最大吸收容量为384.6 mg / g。此外,分配系数(Kd)U [VI]离子与其他受竞争离子形成的[受电子邮件保护的]复合物离子为1.97×10 4  mg / L,并且在模拟海水中对铀(VI)表现出优异的选择性,这很好地说明了吸附剂在海水中的应用。

更新日期:2018-06-19
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