Slow magnetic relaxation in a {CoIICo III2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre†,Dalton Transactions

当前位置： X-MOL 学术 › Dalton Trans. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Slow magnetic relaxation in a {CoIICo III2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre†
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-06-18 00:00:00 , DOI: 10.1039/c8dt01997e
Alexandra Collet _{1,

2,

3,

4,

5} , Gavin A. Craig _{1,

2,

3,

4,

5} , María José Heras Ojea _{1,

2,

3,

4,

5} , Lakshmi Bhaskaran _{6,

7,

8,

9} , Claire Wilson _{1,

2,

3,

4,

5} , Stephen Hill _{6,

7,

8,

9} , Mark Murrie _{1,

2,

3,

4,

5}

Affiliation

We report a trinuclear mixed-valence {Co^IICo^III₂} complex, where the Co^II centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

中文翻译：

在{Co ^II Co ^III₂ }络合物中的慢磁弛豫，该络合物包含高磁各向异性的三角双锥体Co ^II中心†

我们报告了一种三核混合价{Co ^II Co ^III₂ }络合物，其中Co ^II中心采用三角双锥几何形状，从而导致大的易平面磁各向异性和磁场诱导的慢磁弛豫，并具有类似拉曼的弛豫过程。

更新日期：2018-06-18

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11