Synthesis of Arylamines via Non‐Aerobic Dehydrogenation Using a Palladium/Carbon‐Ethylene System,Advanced Synthesis & Catalysis

当前位置： X-MOL 学术 › Adv. Synth. Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Synthesis of Arylamines via Non‐Aerobic Dehydrogenation Using a Palladium/Carbon‐Ethylene System
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-07-06 , DOI: 10.1002/adsc.201800504
Yuya Shimomoto ₁ , Ryosuke Matsubara ₁ , Masahiko Hayashi ₁

Affiliation

The reaction of cyclohexanones with amines proceeded under an ethylene atmosphere in the presence of a catalytic amount of palladium/carbon to afford a variety of arylamines in good to high yields. The present reaction was carried out under completely non‐aerobic conditions, and which is in contrast with the previously reported aerobic system. has wide applicability affording a variety of aromatic amines, and co‐product of the reaction is only gaseous ethane. Thus, this method is environmentally friendly. This protocol was applied intramolecularly to provide a novel method for the construction of quinoline and isoquinoline compounds.

中文翻译：

钯/碳乙烯系统通过无氧脱氢合成芳胺

环己酮与胺的反应在乙烯气氛下，在催化量的钯/碳存在下进行，以高收率或高收率得到各种芳基胺。本反应是在完全无氧的条件下进行的，这与先前报道的有氧系统相反。具有广泛的适用性，可提供多种芳族胺，并且反应的副产物仅是气态乙烷。因此，该方法是环境友好的。该方案在分子内应用，为构建喹啉和异喹啉化合物提供了一种新方法。

更新日期：2018-07-06

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11