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Ordered mesoporous alumina-supported vanadium oxides as an efficient catalyst for ethylbenzene dehydrogenation to styrene with CO2
Catalysis Communications ( IF 3.4 ) Pub Date : 2018-06-18 , DOI: 10.1016/j.catcom.2018.06.016
Cun Zhu , Shuwei Chen , Dahai Pan , Xingyu Cui , Yan Qiao , Ruifeng Li

Ordered mesoporous alumina (OMA)-supported vanadia catalysts with different vanadium loading (denoted as nV/OMA) were employed for ethylbenzene dehydrogenation to styrene with CO2 as soft oxidant, and a commercial γ-Al2O3-supported vanadia catalyst for comparison. The catalytic behavior depends strongly on the vanadium loading and the support properties. With an optimal V loading of 0.8 mmol/g-support, 0.8 V/OMA catalyst exhibits superior catalytic performance than that of 0.8 V/γ-Al2O3, which can be attributed to the excellent structural, textual, and surface properties of OMA support. The important roles played by OMA lies in stabilizing highly dispersed V5+ active species and preventing the coke formation.



中文翻译:

有序介孔氧化铝负载的钒氧化物作为乙苯与CO 2脱氢制苯乙烯的有效催化剂

有序的中孔氧化铝(OMA) -支持钒催化剂具有不同的钒负载(表示为ñ V / OMA)的用于乙苯脱氢制苯乙烯的用CO 2作为温和氧化剂,以及市售的γ-Al 2 ö 3 -支持氧化钒催化剂比较。催化行为在很大程度上取决于钒的负载量和载体性质。用0.8毫摩尔/克-载体,0.8 V / OMA催化剂的最佳V装载表现出优良的催化性能比0.8 V /γ-Al系的2 ö 3,这可以归因于的优异的结构,文本和表面性质OMA支持。OMA发挥的重要作用在于稳定高度分散的V 5+ 活性物质并防止焦炭形成。

更新日期:2018-06-18
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