An organocatalyst bound α-aminoalkyl radical intermediate for controlled aerobic oxidation of iminium ions†,Organic & Biomolecular Chemistry

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An organocatalyst bound α-aminoalkyl radical intermediate for controlled aerobic oxidation of iminium ions†
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2018-06-16 00:00:00 , DOI: 10.1039/c8ob01032c
Abdul Motaleb _{1,

2,

3,

4} , Asish Bera _{1,

2,

3,

4} , Pradip Maity _{1,

2,

3,

4}

Affiliation

A catalyst bound α-aminoalkyl radical intermediate from iminium is developed to control its formation and reactivity with aerobic oxygen. The influence of the catalyst was demonstrated via the ease of radical intermediate formation and its subsequent reactivity, including the first catalyst-controlled enantioselective aerobic oxidation with a chiral phosphite catalyst.

中文翻译：

有机催化剂结合的α-氨基烷基自由基中间体，用于控制亚胺离子的好氧氧化†

研发了一种由催化剂与催化剂结合的亚胺基α-氨基烷基自由基中间体，以控制其形成和与好氧的反应性。通过容易形成自由基中间体及其随后的反应性证明了催化剂的影响，包括使用手性亚磷酸酯催化剂进行的第一催化剂控制的对映选择性好氧氧化反应。

更新日期：2018-06-16

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