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Micromorphological control of porous LaMnO3 and LaMn0.8Fe0.2O3 and its catalytic oxidation performance for CO
Journal of Solid State Chemistry ( IF 3.3 ) Pub Date : 2018-06-05 , DOI: 10.1016/j.jssc.2018.06.002
Xuehui Huang , Pengju Niu , Hongyun Pan , Xiaohui Shang

A molten salt method was adopted to prepare porous LaMnO3 and LaMn0.8Fe0.2O3 with different morphologies, using hierarchical porous MnO2 microspheres (S80, S90, S80-1) as precursors in eutectic NaNO3-KNO3, separately. The results show that perovskite phase LaMn0.8Fe0.2O3 can be formed at 435.5 °C. Spherical porous LaMn0.8Fe0.2O3 can be synthesized at 450 °C for 4 h, which was composed of aggregated nanocrystallites. With morphologies similar to S90 and S80-1, LaMnO3 can also be prepared at 450 °C and 500 °C for 4, respectively. Additionally, the sample LaMn0.8Fe0.2O3 also displayed a higher BET surface area of 55.73 m2/g with an average pore size of about 9.38 nm. The results of CO conversion on each sample showed that LaMn0.8Fe0.2O3 owned the best catalytic activity (T50 = 187 °C and T90 = 200 °C) and it was available to improve the catalytic activity through reducing the molar ratio of La(NO3)3·6H2O and S80-1 to lower the amount of La(OH)2NO3.



中文翻译:

多孔LaMnO 3和LaMn 0.8 Fe 0.2 O 3的微观形貌控制及其对CO的催化氧化性能。

采用共熔NaNO 3 -KNO 3的分层多孔MnO 2微球(S80,S90,S80-1)为前体,采用熔融盐法制备了不同形态的多孔LaMnO 3和LaMn 0.8 Fe 0.2 O 3。结果表明,在435.5℃下可以形成钙钛矿相LaMn 0.8 Fe 0.2 O 3。球形多孔LaMn 0.8 Fe 0.2 O 3可以在450°C下合成4 h,由聚集的纳米微晶组成。具有类似于S90S80-1,LaMnO 3也可以分别在450℃和500℃下制备4。另外,样品LaMn 0.8 Fe 0.2 O 3还显示出55.73m 2 / g的更高的BET表面积,具有约9.38nm的平均孔径。每个样品的CO转化结果表明,LaMn 0.8 Fe 0.2 O 3具有最佳的催化活性(T 50 = 187°C和T 90 = 200°C),并且可以通过降低摩尔比来提高催化活性。的La(NO 33 ·6H 2的O和S80-1降低La(OH)2 NO 3的量

更新日期:2018-07-12
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