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Effect of Y substitution on the structural and magnetic properties of Sm(Fe0.8Co0.2)11.4Ti0.6
Journal of Magnetism and Magnetic Materials ( IF 2.5 ) Pub Date : 2018-06-15 , DOI: 10.1016/j.jmmm.2018.06.042
Masaya Hagiwara , Naoyuki Sanada , Shinya Sakurada

The structural and magnetic properties of (Sm, Y)(Fe0.8Co0.2)12−xTix (x = 0.6, 1) prepared by arc melting are investigated. The formation of the ThMn12 structure was facilitated by the substitution of Sm with Y at low Ti concentrations (x = 0.6), and almost a single phase with the ThMn12 structure was obtained for (Sm0.8Y0.2)(Fe0.8Co0.2)11.4Ti0.6. This suggests that Y plays an important role in stabilizing the ThMn12 structure owing to the decrease in the atomic radius of the rare earth site. The intrinsic magnetic properties of (Sm0.8Y0.2)(Fe0.8Co0.2)11.4Ti0.6 exhibited μ0Ms = 1.50 T, μ0Ha = 11 T, and Tc = 820 K at room temperature.

中文翻译:


Y取代对Sm(Fe0.8Co0.2)11.4Ti0.6结构和磁性能的影响



研究了电弧熔炼制备的(Sm, Y)(Fe0.8Co0.2)12−xTix (x = 0.6, 1)的结构和磁性能。在低Ti浓度(x = 0.6)下,用Y取代Sm有利于ThMn12结构的形成,并且(Sm0.8Y0.2)(Fe0.8Co0.2)几乎获得了具有ThMn12结构的单相)11.4Ti0.6。这表明,由于稀土位点原子半径的减小,Y 在稳定 ThMn12 结构方面发挥着重要作用。 (Sm0.8Y0.2)(Fe0.8Co0.2)11.4Ti0.6的本征磁性能在室温下表现出μ0Ms = 1.50 T、μ0Ha = 11 T和Tc = 820 K。
更新日期:2018-06-15
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