During recent years, the catalytic transformation of CO₂ using silicon‐hydrides as reductants has emerged as a promising methodology that allows the selective reduction of CO₂ to the formate, formaldehyde, methoxide or methane level under mild reaction conditions. Moreover, some catalysts have been employed for the formylation and/or methylation of the N−H bonds of secondary and/or primary amines by their reaction with CO₂ and hydrosilanes. This work summarizes the different catalytic systems that have shown to be efficient for the above‐mentioned reactions. Furthermore, a brief description of the reactions performance and the conditions employed in each case is included.

中文翻译：

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氢化硅的均相催化还原CO2技术

近年来，使用氢化硅作为还原剂对CO ₂进行催化转化已成为一种有前途的方法，该方法可以在温和的反应条件下将CO ₂选择性还原为甲酸盐，甲醛，甲醇盐或甲烷。此外，一些催化剂已经通过其与CO ₂和氢硅烷的反应用于仲胺和/或伯胺的NH键的甲酰化和/或甲基化。这项工作总结了已证明对上述反应有效的不同催化体系。此外，包括对每种情况下反应性能和条件的简要描述。