Porous Organic Polymers Containing Active Metal Centers as Catalysts for Synthetic Organic Chemistry,ACS Catalysis

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Porous Organic Polymers Containing Active Metal Centers as Catalysts for Synthetic Organic Chemistry
ACS Catalysis ( IF 11.3 ) Pub Date : 2018-06-14 00:00:00 , DOI: 10.1021/acscatal.8b01167
Søren Kramer ₁ , Niklas R. Bennedsen ₁ , Søren Kegnæs ₁

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Porous organic polymers (POPs) containing catalytically active mononuclear metal centers can bridge the gap between homogeneous and heterogeneous catalysis. These materials offer catalysts with straightforward control over the active site analogously to homogeneous organometallic catalysts; however, just like classical heterogeneous catalysts, they are easy to separate from reaction mixtures and recycle. The main objective of this Review is to provide an overview of the different types of reactions for synthetic organic chemistry where metal-POP catalysts have been utilized. In addition, a brief description of different synthesis strategies for accessing metal-POPs is included. We also propose a uniform naming system for metal-POP catalysts. Finally, current challenges that could advance the field and facilitate industrial application are discussed.

中文翻译：

含活性金属中心的多孔有机聚合物作为合成有机化学的催化剂

包含具有催化活性的单核金属中心的多孔有机聚合物（POP）可以弥合均相和异相催化之间的差距。与均相有机金属催化剂类似，这些材料为催化剂提供了对活性位点的直接控制。但是，就像传统的多相催化剂一样，它们很容易从反应混合物中分离出来并进行再循环。本综述的主要目的是概述使用金属POP催化剂的合成有机化学不同类型的反应。此外，还简要介绍了用于获取金属POP的不同合成策略。我们还为金属POP催化剂提出了统一的命名系统。最后，

更新日期：2018-06-14

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