Organometallic functionalized non-classical polyoxometalates: synthesis, characterization and electrochemical properties†,Dalton Transactions

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Organometallic functionalized non-classical polyoxometalates: synthesis, characterization and electrochemical properties†
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-06-14 00:00:00 , DOI: 10.1039/c8dt01712c
Panpan Zhang _{1,

2,

3,

4,

5} , Vikram Singh _{1,

2,

3,

4,

5} , Jiage Jia _{1,

2,

3,

4,

5} , Dongdi Zhang _{1,

2,

3,

4,

5} , Pengtao Ma _{1,

2,

3,

4,

5} , Jingping Wang _{1,

2,

3,

4,

5} , Jingyang Niu _{1,

2,

3,

4,

5}

Affiliation

Two monomeric non-classical tellurium-containing heteropolymolybdate-supported metal carbonyl derivatives (NH₄)₅H₃{[Te₂Mo₁₂(OH)O₄₄][Mn(CO)₃]}·18H₂O (1) and (NH₄)₈{[Te₂Mo₁₂(OH)O₄₄][Re(CO)₃]}·13H₂O (2) have been successfully isolated in good yields. Compounds 1 and 2 are the first two examples of metal carbonyl derivatives of heteromolybdate with tellurium as the central atom. These two compounds have been thoroughly characterized by single-crystal X-ray diffraction, elemental analyses, X-ray powder diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and UV-Vis spectroscopy. The electrochemical catalytic activities of 1 and 2 including cyclic voltammetry and catalytic oxidation of nitrite have also been investigated.

中文翻译：

有机金属官能化的非经典多金属氧酸盐：合成，表征和电化学性能†

两个单体非经典含碲杂钼酸负载金属羰基衍生物（NH ₄）₅ H ₃ {[Te ₂ Mo ₁₂（OH）O ₄₄ ] [Mn（CO）₃ ]}·18H ₂ O（1）和（ NH ₄）₈ {[Te ₂ Mo ₁₂（OH）O ₄₄ ] [Re（CO）₃ ]}·13H ₂ O（2）已成功分离出，收率很高。化合物1和2是以碲为中心原子的杂钼酸盐的金属羰基衍生物的前两个例子。这两种化合物已通过单晶X射线衍射，元素分析，X射线粉末衍射，傅里叶变换红外光谱，热重分析和UV-Vis光谱进行了彻底表征。还研究了1和2的电化学催化活性，包括循环伏安法和亚硝酸盐的催化氧化。

更新日期：2018-06-14

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