Selective hydrogenation of amides to alcohols in water solvent over a heterogeneous CeO2-supported Ru catalyst†,Chemical Communications

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Selective hydrogenation of amides to alcohols in water solvent over a heterogeneous CeO2-supported Ru catalyst†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-06-14 00:00:00 , DOI: 10.1039/c8cc02697a
Masazumi Tamura _{1,

2,

3,

4} , Susumu Ishikawa _{1,

2,

3,

4} , Mii Betchaku _{1,

2,

3,

4} , Yoshinao Nakagawa _{1,

2,

3,

4} , Keiichi Tomishige _{1,

2,

3,

4}

Affiliation

CeO₂-supported Ru (Ru/CeO₂) worked as an effective and reusable heterogeneous catalyst for the selective dissociation of the C–N bond in amides, particularly primary amides, with H₂ in water solvent at low reaction temperature of 333 K, and high yields of the corresponding alcohols were obtained from primary amides.

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